I will be updating this as I find more tweaks or mods to make screwy things functional/more acceptable. But between them both, I feel that these are things that should have been done/implemented from the get-go to make this a more pleasant VR experience. Some of which are ini tweaks and others are mods.
So after messing around with FO4 VR a bit and doing much reading on Reddit, I have found quite a few fixes to absolutely infuriating issues.